MALLINCKRODT INC -- POTASSIUM CHLORATE -- 6810-00N068993
===================== Product Identification ===================== Product ID:POTASSIUM CHLORATE MSDS Date:08/09/1985 FSC:6810 NIIN:00N068993 === Responsible Party === Company Name:MALLINCKRODT INC Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORIC ACID, POTASSIUM SALT; (POTASSIUM CHLORATE) CAS:3811-04-9 RTECS #:FO0350000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:MAY CAUSE IRRIT TO RESP TRACT; SYMPS MAY INCL SORE THROAT, COUGHING, HDCH & DIZZ. INGEST: MAY CAUSE NAUS, VOMIT, DIARR, ABDOM PAIN, HEMOLYSIS, METHEMOGLOBINEMIA, CYANOSIS, ANURIA, COMA & CONVULS . MAY CAUSE LIVER & KIDNEY DMG. DEATH MAY OCCUR FROM RENAL FAILURE, GENERALLY IN 4 DAYS. ESTIMATED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: LETHAL DOSE FROM 15 - 30 GRAMS. SKIN: MAY CAUSE IRRIT, REDNESS & PAIN. SOLUTIONS TEND TO BE MORE IRRITATING. EYE: MAY CAUSE IRRITATION, REDNESS & PAIN. CHRONIC: RPTD INGESTION OF SMALL AMTS MAY CAUSE LOSS OF APPETITE & WEIGHT LOSS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BRTHG DFCLTY. INGEST:INDUCE VOMIT IMMED BY GIVING GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. CALL MD IMMED. SKIN:REMOVE ANY CONTAMD CLTHG. WIPE OFF EXCESS FROM SKIN. WASH SKIN W/SOAP & WATER FOR AT LEAST 15 MINS. GET MED ATTN IF IRRIT DEVEL/PERSISTS. EYE: WASH W/PLENTY OF WATER FOR AT LEAST(SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CNTNRS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:CONT W/OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT COMBUST. EXPLODES W/SULFURIC ACID. NOT COMBUST, BUT IS STRONG OXIDIZER & ITS HEAT OF RXN(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK/SPILL. CLEANUP PERS SHOULD WEAR PROT CLTHG & NIOSH/MSHA APPRVD RESP EQUIP SUITABLE FOR FLAMM & FIRE-PROMOTING MATLS. CAN CAUSE PAPER/WOOD TO IGNITE. SWEEP UP & CNTNRIZE FOR RECLAMATI ON/DISP. WET SWEEPING MAY BE USED TO AVOID(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN COOL, DRY, VENT AREA. PROT AGAINST PHYSICAL DMG. Other Precautions:ISOLATE FROM INCOMPATIBLE SUBSTANCES. SEPARATE FROM COMBUSTIBLE, ORGANIC/OTHER READILY OXIDIZABLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO THE DUST IS APPARENT, A NIOSH/MSHA DUST/MIST RESPIRATOR MAY BE WORN. FOR EMERGENCIES, A NIOSH/MSHA APPROVED SCBA MAY BE NECESSARY. Ventilation:A LOC EXHST SYS WHICH CAPTURES CONTAM AT ITS SOURCE IS RECOMM TO PVNT DISPERSION OF CONTAMD INTO WORKROOM AIR. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA. WEAR CLEAN BODY-COVERING CLTHG. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP:DECOMP @ 400C(752F). SOLUB IN H*2O:7G/100G WATER @ 203C(683F). EXPLO HAZ:W/REDUCING AGENTS/COMBUSTS MAY CAUSE IGNIT. WHEN HEATED, RELEASES O*2 WHICH INCR COMBUST. FIRST AID PROC:15 MIN. IF IRRIT DE VEL, GET MD ATTN. SPILL PROC:DUST DISP.DISSOLVE MATL TO REMOVE FROM PAPER/WOOD. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Melt/Freeze Pt:M.P/F.P Text:673F,356C Spec Gravity:2.3 Solubility in Water:SUPP DATA Appearance and Odor:WHITE CRYSTALS OR POWDER. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES IODIDES, TARTARIC ACID, ALUMINUM, ORGANIC MATTER AND MANY OTHER OXIDIZABLE SUBSTANCES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE & STORAGE. Hazardous Decomposition Products:EMITS TOXIC FUMES OF CHLORINE & POTASSIUM OXIDE WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO A RCRA APPRVD WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.