ALDON CORPORATION -- IODINE -- -
===================== Product Identification ===================== Product ID:IODINE MSDS Date:03/11/1999 FSC:NIIN:Submitter:D DG === Responsible Party === Company Name:ALDON CORPORATION Address:1533 W HENRIETTA RD City:AVON State:NY ZIP:14414-9508 Country:US Info Phone Num:716-226-6177 Emergency Phone Num:716-226-6177/800-424-6177 Resp. Party Other MSDS Num.:IX 120 Preparer's Name:MICHEAL RASZEJA Chemtrec Ind/Phone:(800)424-9300 CAGE:6V042 === Contractor Identification === Company Name:AL-DON CHEMICALS INC Address:1533 W HENRIETTA RD Box:City:AVON State:NY ZIP:14414-9508 Country:US Phone:716-226-6177 CAGE:6V042 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE CAS:7553-56-2 RTECS #:NN1575000 = Wt:100. OSHA PEL:C1 MG/M3;C0.1 PPM ACGIH STEL:C1.0 MG/M3;C0.1 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL HUMAN LDLO:2000 MG/KG.(ACGIH 1992) Health Hazards Acute and Chronic:TARGET ORGANS AFFECTED: CIRCULATORY SYSTEM AND KIDNEYS. SEVERE LACHRYMATOR. EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES, SKIN. MAY CAUSE SPASM, CHEMICAL P NEUMONITIS, COUGHING, WHEEZING, SHORT OF BREATH, HEADACHE, NAUSEA AND VOMITING. Effects of Overexposure:SEVERE LACHRYMATOR. EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES, SKIN. MAY CAUSE SPASM, CHEMICLAL PNEUMONITIS, COUGHING, WHEEZING, SHORT OF BREATH, HEADAC HE, NAUSEA AND VOMITING. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF MILK, FOLLOWED BY A STARCH, FLOUR,OR EGG WHITE, AS WATER SOLUTION. GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO A N UNCONSCIOUS PERSON. EYES: FLUSH THROUGHLY WITH WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS S TOPPED, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH THROUGHLY WITH WATER. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY IN QUANTITIES DEPENDING UPON THE SERIOUSNESS OF THE FIRE. Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.(1996 EMERGENCY RESPONSE GUIDBOOK, DOT P 5800.7, GUIDE PAGE NO. 154). Unusual Fire/Explosion Hazard:SUBLIMES AT ORDINARY TEMPERATURES YIELDING A VAPOR, VIOLET IN COLOR AND CORROSIVE TO METALS AND TO ALL BODY TISSUES. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. WEAR FULL PROTECTIVE CLOTHING (SAFETY GOGGLES, GAS MASK AND GLOVES ARE RECOMMENDED) AND PROVIDE VENTILATION. COVER WITH LIME OR SODA ASH. SWEEP UP AND PLACE IN A 5 -10% SODIUM THIOSULFATE SOLUTION. Neutralizing Agent:5-10% SODIUM THIOSULFATE SOLUTION. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT AND DIRECT SUNLIGHT. WASH THROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. READ LABEL ON CONTAINERBEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH SKIN, EYES AND CLOTHING. CONTACT WITH SKIN WILL LEAVE YELLOW IDOINE STAIN. USE WITH ADEQUATE VENTILATION. REMOVE ALL CONTAMINATED CLOTHING AND SHOES. DECONTAMINATE BEFORE REUSE. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD, OR HOUSEHOLD USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN THE LABORATORY, WORK IN A FUME HOOD OR IF IODINE VAPORS ARE PRODUCED IN WORK AREA, WEAR A NIOSH/MSHA -APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) RECOMMENDED. Protective Gloves:RUBBER Eye Protection:CHEMICAL SAFETY GOGGLES. Other Protective Equipment:SMOCK, APRON, EYE WASH STATION, VENTILATION, GOGGLES WITH SIDE SHIELD, PROPER GLOVES, SAFETY SHOWER. Supplemental Safety and Health WARDS NATURAL SCIENCE PART NUMBER: 37W2371. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=183.9C, 363.F Melt/Freeze Pt:=112.8C, 235.F Vapor Pres:0.2 MM HG AT 20C Vapor Density:4.4(AIR=1) Spec Gravity:4.93 Evaporation Rate & Reference:SUBLIMES AT ORDINARY TEMP Solubility in Water:0.029 G PER 100 ML.@ 20C Appearance and Odor:BLUISH-BLACK SCALES, CRYSTALS, METALLIC LUSTER, CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT OF GASEOUS AMMONIA OR ITS SOLUTION WITH FREE IODINE SHOULD BE AVOIDED TO PREVENT THE FORMATION OF THE EXPLOSIVE "NITROGEN IODINE". ACETALDEHYDE SODIUM AZIDE, SODIUM HYDRIDE. CORRODES STEEL. Stability Condition to Avoid:EXCESSIVE TEMPERATURES OR HEAT WILL INCREASE RATE OF SUBLIMATION. Hazardous Decomposition Products:ELEMENTAL FORM. CANNOT PRODUCE DECOMPOSITION PRODUCTS. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TWA: (CEILING LIMIT) 0.1 PPM; 1 MG/M3 (AIR). TO XUCITY: ORAL-HUMAN LDLO; 2000 MG/KG. (ACGIH 1992-93). DANGER! CORROSIVE! CAUSES SKIN AND EYE BURNS. MAY BE FATAL IF SWALLOWED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. HARMFUL IF INHALED. MAY CAUSE DELAYED LUNG INJURY. SUBLIMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE, OR LOCAL LAWS. WORK IN A VENTILATION HOOD. WEAR PROPER SAFETY EQUIPMENT, COLLECT WASTE IODINE IN LARGE BEAKER. COVER WITH LARGE VOLUME OF WATER. SLOWLY ADD, WHILE STIRRING SODA ASH OR SODIUM THIOSULFATE TILL IODINE HAS BEEN DISSOLVED AND SOLUTION IS COLORL ESS. FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. =================== MSDS Transport Information =================== Transport Information:D.O.T. : CORROSIVE SOLIDS, N.O.S. ,(IODINE), CLASS 8, UN 1759, PGI I I. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.