RHONE-POULENC -- TRISODIUM PHOSPHATE -- 6810-00N079562
===================== Product Identification ===================== Product ID:TRISODIUM PHOSPHATE MSDS Date:09/12/1996 FSC:6810 NIIN:00N079562 === Responsible Party === Company Name:RHONE-POULENC Address:CN 7500 City:CRANBURY State:NJ ZIP:08512-7577 Country:US Info Phone Num:800-243-5052 Emergency Phone Num:800-334-7577;800-424-9300(CHEMTREC) CAGE:RHONP === Contractor Identification === Company Name:RHONE-POULENC Address:9808 BLUEGRASS PKWY Box:125 City:LOUISVILLE State:KY ZIP:40299 Country:US Phone:502-635-8877 CAGE:RHONP ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID, TRISODIUM SALT, DODECAHYDRATE; (SODIUM PHOSPHATE, TRIBASIC) CAS:10101-89-0 RTECS #:TC9575000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT:VICTIM IS NOT BRTHG, ADMIN CPR. SEEK ATTN. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-3 GLASSES OF (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:WATER TO DRINK & DO NOT INDUCE VOMIT. SEEK IMMED MED ATTN. DO NOT LEAVE VICTIM UNATTENDED. TO PVNT ASPIR (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:OF SWALLOWED PROD, LAY VICTIM ON SIDE W/HEAD LOWER THAN WAIST. VOMIT MAY OCCUR SPONT. IF VOMIT OCCURS & (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:VICTIM IS CONSCIOUS, GIVE WATER TO FURTHER DILUTE CHEM. NOTE TO PHYS:ALL TREATMENTS SHOULD BE BASED ON (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:OBSERVED SIGNS & SYMPS OF DISTRESS IN PATIENT. CONSIDERATION SHOULD BE GIVEN TO POSSIBILITY THAT OVEREXP (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:TO MATLS OTHER THAN THIS PROD MAY HAVE OCCURRED. TREAT SYMPTOMATICALLY. NO SPECIFIC ANTIDOTE AVAIL. INGEST (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OF LG QTYS OF PHOSPHATE SALTS (>1 GRAMS FOR ADULT) MAY CAUSE AN OSMOTIC CATHARSIS RSLTG IN DIARR & PROBABLE(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ABDOM CRAMPS. LGR DOSES SUCH AS 4-8 GRAMS WILL ALMOST CERTAINLY CAUSE THESE EFTS IN EVERYONE. IN HEALTHY (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:INDIVIDUALS MOST OF INGESTED SALT WILL BE EXCRETED IN FECES W/DIARR &, THUS, NOT CAUSE ANY SYSTEMIC TOX. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:DOSES >10 GRAMS HYPOTHETICALLY MAY CAUSE SYSTEMIC TOX. TREATMENT SHOULD TAKE INTO CONSIDERATION (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:BOTH ANIONIC & CATION PORTION OF MOLECULE. FOLLOWING TREATMENTS SHOULD BE CONSIDERED FOR SPECIFIC (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:GROUP(S) OF PHOSPHATE SALTS FOUND IN THIS PROD. ALL PHOSPHATE SALTS, EXCEPT CALCIUM SALTS, HAVE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:HYPOTHETICAL RISK OF HYPOCALCEMIA, SO CALCIUM LEVS SHOULD BE MONITORED. AMMONIUM SALTS HAVE HYPOTHETICAL(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:RISK OF AMMONIA TOX. IN ADDN TO CALCIUM LEVELS, AMMONIA & PHOSPHATE LEVELS SHOULD BE MONITORED. POTASSIUM(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:SALTS HAVE HYPOTHETICAL RISK OF HYPERKALEMIA WHICH CAN CAUSE CARD ARRHY. IN ADDN TO CALCIUM LEVELS, (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:POTASSIUM & PHOSPHATE LEVELS SHOULD BE MONITORED. ALSO CONSIDER CONTINUOUS EKG MONITORING TO DETECT (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:HYPERKALEMIA. SODIUM SALTS HAVE HYPOTHETICAL RISK OF HYPERNATREMIA. IN ADDN TO CALCIUM LEVELS, SODIUM (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:AND PHOSPHATE LEVELS SHOULD BE MONITORED. RTECS #:9999999ZZ Ingred Name:SPILL PROC:TO PREDETERM PLAN. WEAR APPROPRIATE PPE. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DIFFERENT FROM FED LAWS & REGS. CONSULT STATE & LOC REGS REGARDING PROPER DISP OF THIS MATL. RTECS #:9999999ZZ Ingred Name:RESP PROT:FACE POS PRESS AIR-SUPPLIED RESP EQUIPPED W/EMER ESCAPE AIR SUPPLY UNIT/USE NIOSH APPRVD SCBA UNIT. RTECS #:9999999ZZ Ingred Name:VENT:CTL TECHNIQUES MAY BE USED TO EFTIVELY MIN EMPLOYEE EXPOS:LOC EXHAUST VENT @ POINT OF GENERATION. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:FACE CAREFULLY BEFORE EATING, DRINKING, USING TOCACCO, COSMETICS/TOILET. CONT NEHC FOR MORE INFO . RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 7400 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE BURNS, IRRIT, PERM DMG TO CORNEA. SKIN:MAY CAUSE BURNS, IRRIT, IRRIT IS LIKELY TO BE MORE SEV IF SKIN IS MOIST/WET. INHAL:MAY CAUSE IRRIT, CHEST PAIN, SHORTNESS OF BREATH, UPPER RE SP TRACT IRRIT, SERIOUS DMG TO LUNG TISS & RESP TRACT. INGEST:MAY CAUSE IRRIT, CORR, BURNS TO MOUTH & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:ESOPHAGUS. ASPIR OF SWALLOWED/VOMITED PROD CAN CAUSE SEV PULM COMPLICATIONS. TOX INFO:EYE:IRRIT, RABBIT. CORR. SKIN:IRRIT, RABBIT. NON-IRRITATING. UNCOVERED. DRY SKIN(AT 4HRS). SKIN-IRRIT, RA BBIT. CORR. COVERED. MOIST SKIN (AT 24 HRS.). Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:HOLD EYELIDS OPEN & FLUSH W/STEADY, GENTLE STREAM OF WATER FOR @ LST 15 MINS. SEEK IMMED MED ATTN, PREF W/OPHTHALMOLOGIST. IF PHYS IS NOT IMMED AVAIL, EYE IRRIGATION SHOULD BE CONTINUED FOR ADDNL 15 MINS. IF IT IS NEC TO TRANSPORT PATIENT TO PHYS & EYE NEEDS TO BE BANDAGES, USE DRY STERILE CLOTH PAD & COVER BOTH EYES. SKIN:IMMED WASH W/PLENTY OF SOAP & WATER FOR @ LST 15 MINS. SEEK (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT COMBUSTIBLE. USE EXTINGUISHING METHOD SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT COMBUSTIBLES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP/VACUUM UP & PLACE IN APPROP CLSD CNTNR. CLEAN UP RESIDUAL MATL BY WASHING AREA W/WATER. RUNOFF FROM FIRE CTL/DILUTION WATER MAY CAUSE POLLUTION. PVNT MATL FROM ENTERING PUBLIC SEWER SYS/ANY WATE RWAYS. LG SPILLS SHOULD BE HNDLD ACCORDING(ING 20) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN AREA THAT IS COOL, DRY, WELL-VENTILATED, AWAY FROM FOODSTUFFS/ANIMAL FEED. STORE IN TIGHLY CLSD CNTNRS. DO NOT INGEST. Other Precautions:AVOID DIRECT/PRLNGD CONT W/SKIN & EYES. ATTENTION:POTNTLY DEADLY CO GAS FORM IN ENCLOSED AREAS/TANKS WHEN ALKALINE PRODS CONT MATLS THAT CONTAIN SUGERS. FOR MORE SPECIFIC INFORMATION CONT NEHC . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN RESPS ARE REQD, SELECT NIOSH APPRVD EQUIP BASED ON ACTUAL/POTNTL AIRBORNE CONDS & I/A/W APPROP REGULATORY STDS &/OR INDUST REC. UNDER CNDNTS IMMED DANGEROUS TO LIFE/HLTH, OR EMER CNDTNS W/UNKNOWN CONCS, USE NIOSH APPRVD FULL-(ING 22) Ventilation:WHERE ENGINEERING CTLS ARE INDICATED BY USE CNDTNS/POTNTL FOR EXCESS EXPOS EXISTS, FOLLOWING TRADITIONAL EXPOS (ING 23) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . SUITABLE LONG-SLEEVED CLTHG(I.E., SHIRTS & PANTS). Work Hygienic Practices:DO NOT STORE, USE, &/OR CONSUME FOODS, BEVERAGES. TOBACCO PRODS/COSMETICS IN AREAS MATL IS STORED. WASH HANDS & (ING 24) Supplemental Safety and Health PH:11.8 @ 1 WT/WT%. SOL IN H*2O:SOLUBLE 30 WT/WT% @ 25C. FIRST AID PROC:MED ATTN. REMOVE CONTAMD CLTHG & SHOES WHILE WASHING. CLEAN CONTAMD CLTHG & SHOES BEFORE RE-USE/DISCARD IF CANNOT BE THORO CLEAN ED. INHAL:REMOVE FROM SOURCE OF EXPOS &ASSURE VICTIM IS BRTHG. IF BRTHG IS DFCLT, ADMIN OXYG, IF AVAIL. IF (ING 2) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:167F,75C pH:SUPDAT Evaporation Rate & Reference:NOT KNOWN Solubility in Water:SUPP DATA Appearance and Odor:WHITE GRANULES SOLID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, MAGNESIUM. Stability Condition to Avoid:MOISTURE. Hazardous Decomposition Products:UNDER FIRE CNDTNS:OXIDES OF SODIUM. OXIDES OF PHOSPHOROUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CHEM ADDITIONS, PROCESSING/OTHERWISE ALTERING MATL MAY MAKE WASTE MANAGEMENT INFO PRESENTED IN MSDS INCOMPLETE, INACCURATE/OTHERWISE INAPPROP. PLEASE BE ADVISED STATE & LOC REQUIREMENTS FOR WASTE DISP MAY BE MORE RESTRICTIVE/OTHERWISE (ING21) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.