STARTEX CHEMICAL INC -- PAINT THINNER -- 8010-01-441-5940
===================== Product Identification ===================== Product ID:PAINT THINNER MSDS Date:11/01/1999 FSC:8010 NIIN:01-441-5940 Status Code:A === Responsible Party === Company Name:STARTEX CHEMICAL INC Address:5 HACKBERRY LANE Box:3087 City:CONROE State:TX ZIP:77305 Country:US Info Phone Num:409-539-6244 Emergency Phone Num:(800)424-9300 Preparer's Name:HENRY SIMMONS Chemtrec Ind/Phone:(800)424-9300 CAGE:0YFV5 === Contractor Identification === Company Name:STARTEX CHEMICAL INC Address:5 HACKBERRY LANE Box:3087 City:CONROE State:TX ZIP:77305 Country:US Phone:409-539-6244 CAGE:0YFV5 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 OSHA PEL:2900 MG/M3;500 PPM ACGIH TLV:525 MG/M3;100 PPM Ingred Name:N-NONANE CAS:111-84-2 RTECS #:RA6115000 Minumum % Wt:1. Maxumum % Wt:6. ACGIH TLV:1050 MG/M3;200 PPM Ingred Name:N-OCTANE CAS:111-65-9 RTECS #:RG8400000 Minumum % Wt:1. Maxumum % Wt:3. OSHA PEL:2350 MG/M3;500 PPM ACGIH TLV:1400 MG/M3;300 PPM ACGIH STEL:1750 MG/M3;375 PPM Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Effects of Overexposure:EFFECTIVE AND HAZARDS OF EYE CONTACT: MAY CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION AND CONJUNCTIVITIS. EFFECTS AND HAZARDS OF SKIN CONTACT: PROLONGED OR REPEATED CONTACT MAY CAUSE MOD ERATE IRRITATION, DEFATTING (CRACKING), REDNESS, ITCHING, INFLAMMATION, DERMATITIS AND POSSIBLE SECONDARY INFECTION. EFFECTS AND HAZARDS OF INHALATION: NASAL AND RESPIRATORY TRACT IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING EXCITATION, EUPHORIA, SEIZURES, COMA, RESPIRATORY ARREST AND SUDDEN DEATH COULD OCCUR AS A RESULT OF LONG TERM EXPOSURE TO VAPORS. EFFECTS AND HAZARDS OF INGESTION: TH IS PRODUCT MAY BE HARMFUL IF SWALLOWED. Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, HEART, CENTRAL NERVOUS AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:TREATMENT FOR EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. EYELIDS SHOULD BE HELD AWAY FROM THE EYEBALL TO ENSURE RINSING. TREATMENT FOR SKIN CONTACT: WASH EXPOS ED AREAS THROROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING CLOTHING PROMPTLY AND LAUNDER BEFORE REUSE. TREATMENT FOR INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT. ENSURE CLEA R AIRWAY AND ADMINISTER OXYGEN. IF NOT BREATHING, APPLY ARTIFICIAL RESPIRATION OR CARDIOPULMONARY. TREATMENT FOR INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITIN G. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:=40.6C, 105.F Autoignition Temp:>204.4C, 400.F Lower Limits:.9% Upper Limits:6.0% Fire Fighting Procedures:FLAMMABLE LIQUID. USE DRY CHEMICAL. FOAM OR CABON DIOXIDE TO EXTINGUISH THE FIRE. CONSULT FOAM MANUFACTURER FOR APPROPRIATE MEDIA, APPLICATION RATES AND WATER/FOAM RATIO. WATER CAN BE USED TO COOL FIR E EXPOSED CONTAINERS, STRUCTURES AND TO PROTECT PERSONNEL. IF A LEAK A OR SPILL HAS NOT IGNITED, VENTILATE AREA . Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOSED TO HEAT OR FLAME. VAPORS FORM FLAMMABLE OR EXPLOSIVE MIXTURES WITH AIR AT ROOM TEMPERATURE. VAPOR OR GAS MAY SPREAD TO DISTANT IGNITION SOURCES SOURCES (PILOT LIGHTS, WELDING EQ UIPMENT, ELETRICAL EQUIPMENT, ETC.) AND FLASH BACK. VAPORS MAY ACCUMULATE IN LOW AREAS. ================== Accidental Release Measures ================== Spill Release Procedures:IF FACILITY OR OPERATION HAS AN "OIL OR HAZARDOUS SUBSTANCE CONTIGENCY PLAN" ACTIVATES ITS PROCEDURES. STAY UPWIND AND AWAY FROM SPILL. WEAR APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROT ECTION AS CONDITIONS WARRANT. DO NOT ENTER OR STAY IN AREA UNLESS MONITORING INDICATES THAT IT IS SAFE TO DO SO. ISOLATE HAZARD AREA AND RESTRICT ENTRY TO EMERGENCY CREW. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN COOL, DRY, ISOLATED AND WELL VENTILATED AREA AWAY FROM HEAT. SOURCES OF IGNITION AND INCOMPATIBLE MATERALS. USE NON-SPARKING TOOLS AND EXPLOSION PROOF EQUIPMENT. Other Precautions:TANKS, VESSELS, OR OTHER CONFINED SPACES WHICH HAVE BEEN CONTAINED PRODUCT SHOULD BE FREED OF VAPORS BEFORE ENTERING. THE CONTAINER SHOULD BE CHECKED WITH AN EXPLOSIMETER FOR SAFETY AND AN OXYGEN METE R TO ENSURE A SAFE BREATHING ATMOSPHERE BEFORE ENTRY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS OR FOR PRODUCT OR COMPONENTS ARE EXCEEDED, NIOSH EQUIPMENT SHOULD BE WORN. PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED BY ADEQUATELY TRAINED PERSONNEL, BASED ON THE C ONTAMINANTS. THE DEGREE OF POTENTIAL EXPOSURE AND PUBLUSHED RESPIRATORY PROTECTION FACTORS. THIS EQUIPMENT SHOULD BE AVAILABLE FOR NONROUTINE AND EMERGENCY USE. Ventilation:AVOID BREATHING MIST AND VAPOR. USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECHANICAL VENTILATION MAY BE NECESSARY TO REDUCE VAPOR CONCENTRATIONS. Protective Gloves:KEEP AWAY FROM SKIN. SKIN CONTACT CAN BE MINIMIZED BY WEARING PROTECTIVE GLOVES Eye Protection:KEEP AWAY FROM EYES. EYE CONTACT CAN BE AVOIDED BY WEARING SAFETY GLASSES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=154.4C, 310.F B.P. Text:310-400F Vapor Pres:.1 PSI @ 100F Spec Gravity:.77 @ 60 Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER WHITE LIQUID WITH MILD HYDROCARBON ODOR Percent Volatiles by Volume:MODERATE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING AGENTS (PEROXIDE, DICHROMATE, PERMANGANATE, CHLORINE, ETC.) STRONG ACIDS, CAUSTICS AND HALOGENS. Stability Condition to Avoid:HEAR, SPARKS OR OPEN FLAMES, STATIC ELETRICITY OR ANY OTHER POTENTIAL IGNITION SOURCES SHOULD BE AVOIDED. PREVENT VAPOR ACCUMULATION. DO NOT SWITCH LOAD. Hazardous Decomposition Products:COMBUSTION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND REACTIVE HYDROCARBONS (ALDEHYDES, AROMATICS, ETC.) =================== Toxicological Information =================== Toxicological Information:C9 AROMATICS PRODUCED TOXIVITY IN BOTH MOTHERS AND THEIR FETUSES WHEN THE LABORATORY ANIMALS WERE EXPOSED TO SIGNIFICANT CONCENTRATIONS OF C9 AROMATICS THROUGHOUT THEIR PREGNACY. MINERAL SPIRITS (STOD DARD SOLVENT) CAN AFFECT THE BODY IF IT IS INHALED, COMES IN CONTACT WITH THE EYES OR SKIN, OR IS SWALLOWED. THE VAPOR IS A MILD NARCOTIC AND A MUCOUS MEMBRANE IRRITANT. SINCE IT CONTAINS ALIPHATIC AN D AROMATIC HYDROCARBONS IN VARYING CONCENTRATIONS. TOXICOLOGIC OPNION IS BASED UPON DEDUCTIONS AS TO THE RELATIVE HEALTH HAZARD OF THE DIFFERENT FRACTIONS. THE VAPOR OF THE ALIPHATIC FRACTIONS IS CHIE FLY NONANE AND ISODECANE. ===================== Ecological Information ===================== Ecological:NONE SPECIFIED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF MATERIAL IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS. CONTACT STATE AND FEDERAL REGULATORS TO DETERMINE WHETHER THE MATERIAL SHOULD BE CLASSIFIED AS A HAZARDOUS WASTE O R INDUSTRIAL WASTE AND HANDLED ACCORDINGLY. USE LINCENSED TRANSPORTER AND DISPOSAL FACILITY. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302/304 EXTREMELY HAZARDOUS SUBSTANCES: NONE. SECTION 311 HAZARD CATERGORY: ACUTE, CHRONIC, AND FIRE. SECTION 313 TOXIC CHEMICALS: 1,2,4 TRIMETHYLBENZENE 5% MAXIMUM State Regulatory Information:THIS PRODUCT CONTAINS BENZENE AND TOLUENE, CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.