FRANKLIN INTERNATIONAL INC -- TITEBOND II PREMIUM WOOL GLUE, 4999 -- 8040-00N055883
===================== Product Identification ===================== Product ID:TITEBOND II PREMIUM WOOL GLUE, 4999 MSDS Date:02/23/1996 FSC:8040 NIIN:00N055883 === Responsible Party === Company Name:FRANKLIN INTERNATIONAL INC Address:2020 BRUCK ST City:COLUMBUS State:OH ZIP:43207 Country:US Info Phone Num:800-877-4583 Emergency Phone Num:614-445-1300;800-424-9300(CHEMTREC) CAGE:FO059 === Contractor Identification === Company Name:FRANKLIN INTERNATIONAL Address:2020 BRUCK STREET Box:City:COLUMBUS State:OH ZIP:43207 Country:US Phone:800-877-4583/614-445-1493 CAGE:25589 Company Name:FRANKLIN INTERNATIONAL Address:2020 BRUCK ST City:COLUMBUS State:OH ZIP:43207 Phone:800-877-4583 CAGE:FO059 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-BUTOXY ETHOXY)-; (GLYCOL ETHER) CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 0.33% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, VINYL ESTER; (VINYL ACETATE) (SARA 302/313) (CERCLA) CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: 0.05% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15,A3 STEL;95 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.05% OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9495 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:POLYVINYL ACETATE EMULSION CAS:113408-93-8 Fraction by Wt: 3%< OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYVINYL ALCOHOL CAS:25213-24-5 Fraction by Wt: 3%< OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM CHLORIDE, HEXAHYDRATE, ALUMINUM CHLORIDE) CAS:7784-13-6 RTECS #:BD0530000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACRYLAMIDE, N-(HYDROXYMETHYL)-,(N-METHYLOLACRYLAMIDE) CAS:924-42-5 RTECS #:AS3600000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:IRRIT. EXPOS TO FORMALDEHYDE VAP CAN CAUSE CANCER IN THE RESP SYS OF RATS. THERE IS LTD EVIDENCE TO (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:SUGGEST THAT FORMALDEHYDE VAPOR MAY CAUSE CANCER IN HUMANS. TOXICOLOGICAL INFO:IRRIT TO THE NOSE & THROAT(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:HAS BEEN OBSERVED IN PEOPLE EXPOSED TO FORMALDEHYDE VAP AT LEVELS IN EXCESS OF 1 PPM. NORMAL BRTHG MAY (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:BE SERIOUSLY IMPAIRED AT LEVELS ABOVE 10 PPM & SERIOUS LUNG DMG CAN OCCUR AT LEVELS ABOVE 50 PPM.SOLNS OF(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:FORMALDEHYDE CAN IRRIT THE SKIN & EYES. LIFETIME INHAL OF FORMALDEHYDE AT AIRBORNE CONCS ABOVE 5 PPM (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:HAVE CAUSED NASAL TUMORS IN EXPERIMENTAL ANIMALS. HOWEVER, EPIDEMIOLOGY (HUMAN) STUDIES FAILED TO LINK (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:CANCER IN HUMANS W/OCCUP EXPOS TO FORMALDEHYDE. TWO YEAR ANIMAL TESTS (INHAL) AT 50, 200 & 600 PPM OF (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:VINYL ACETATE MONOMER HAVE SHOWN THAT SOME ANIMALS IN THE 600 PPM GROUP DEVELOPED TURMORS. THERE IS (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:NO EVIDENCE OF HUMAN CARCINOGENICITY. ACUTE & CHRONIC HEALTH EFFECTS ARE NOT EXPECTED AS LONG AS GOOD (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:INDUSTRIAL HYGIENE AND SAFETY PRECAUTIONS ARE FOLLOWED. RTECS #:9999999ZZ Ingred Name:OTHER PREC:PROD RESIDUES & VAPORS. AVOID PRLNG/RPTD CONTACT WITH/SKIN. AVOID BREATHING VAPORS FROM HEATED MATERIALS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:NOTE:THIS PROD CONTAINS RESIDUAL VINYL ACETATE MONOMER AT LEVELS BELOW OSHA REPORTABLE CONCS. THE DATA IN SECTION 2 IS PROVIDED FOR INFO PURPOSES ONLY. THIS PROD CNTNS FORMALDEHYDE AT LEVELS BY OSHA R EPORTABLE CONCS. THE DATA IN SECTION 2 IS PROVIDED FOR INFO PURPOSES ONLY. REFER TO CFR 1910.1048 (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:FOR GUIDANCE IN EVALUATING & MAINTAIN A SAFE WORK ENVIRONMENT. ACUTE:INHAL:CTNS RESIDUAL VINYL ACETATE MONOMER & FORMALDEHYDE (SEE SECTION 2). MAY CAUSE HDCHS & DIZZ. VAP &/AEROSOLS WHICH MAY BE FORMED AT ELEVATED TEMP MAY BE IRRIT TO EYES & RESP TRACT. NO REPORTED INCIDENTS OF ADVERSE HLTH (SUPDAT) Medical Cond Aggravated by Exposure:NONE INDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGEST:CALL POISON CONTROL CENTER IMMED. FOLLOW THEIR SPECIFIC INSTRUCTIONS. DO NOT INDUCE VOMITING. ASPIRATION INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS. SKIN:WASH WITH SOAP & WATER. CONTACT A PHYSIC IAN IF IRRIT DEVELOPS OR PERSISTS. EYE:HOLD EYELIDS APART & FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEEK MED ATTN. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F,>93C Extinguishing Media:WATER IF PRODUCT HAS DRIED. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAM TECHNIQUES:USE SUITABLE ABSORB TO DIKE THE SPILL. CLEAN-UP:IF POSS PUMP LIQ INTO AN APPRVD CNTNR/SPREAD ABSORB OVER SPILL & SHOVEL (USE NON-SPARKING EQUIP) PROD/ABSORB MIX INTO APPRVD CNTNR. IF PROD HAS DRIED, SCRAP UP & PLACE IN APPRVD CNTNR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. STORE AT TEMP BETWEEN 50F AND 90F. KEEP OUT OF THE REACH OF CHILDREN. OPEN CONTAINEER IN WELL VENTILATED AREA. Other Precautions:EMPTY DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO A RECONDITIONER/PROPERLY DISPOSEDS OF. USE ONLY IN WELL VENT AREA. FOLLOW ALL MSD/LABEL PRECAUTIONS EVEN AFTER CNTNR IS EMPTIED. CNTNRS MAY RETAIN (ING 20) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE EXPOSURE LIMITS ARE EXCEEDED SELECT A NIOSH APPROVED RESPIRATOR WITH APPROPRIATE PROTECTION FACTOR AND CARTRIDGE FOR THE SPECIFIC CONTAINMENTS. FOLLOW REQUIREMENTS FOR RESPIRATORY PROTECTION IN OSHA 1910.134. Ventilation:USE LOCAL EXHAUST AS NEEDED TO MAINTAIN OCCUPATIONAL EXPOSURE LIMITS. MAINTAIN STANDARD PLANT VENTILATION. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EFTS OF OVEREXP:AFFECTS RSLTG FROM INGEST OF VAPS AT ROOM TEMP. INGEST:NO HAZ EXPECTED IN NORMAL INDUSTRIAL USE. DO NOT EAT, DRINK/SMOKE AROUND CHEM. FOLLOW GOOD HYGIENE PRACTICES. SKIN:WILL NOT BE AB SORBED THRU SKIN. EYE:SUBSTANCE MAY CAUSE MOD EYE (ING 10) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:210F,99C Spec Gravity:1.09044(H*2O=1) VOC Pounds/Gallon:14 pH:3 Evaporation Rate & Reference:FASTER THAN N-BU AC Solubility in Water:DISPERSIBLE IN WATER Appearance and Odor:LIQUID CREAM, MILD ODOR Percent Volatiles by Volume:52 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND BASES. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:OXIDES OF CARBON AND MONOMER MAY BE RELEASED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. CONTAINER DISPOSAL: DISPOSAL OF THIS CONTAINER SHOULD COMPLY WITH ALL APPLICALE FEDERAL STATE AND LOCAL R EGULATIONS. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.