FISHER SCIENTIFIC CO -- SILVER OXIDE -- 6810-00-458-7935
===================== Product Identification ===================== Product ID:SILVER OXIDE MSDS Date:04/02/1997 FSC:6810 NIIN:00-458-7935 === Responsible Party === Company Name:FISHER SCIENTIFIC CO Address:585 ALPHA DR City:PITTSBURGH State:PA ZIP:15238-2911 Country:US Info Phone Num:410-526-8300 Emergency Phone Num:412-526-8300 201-796-7100 CAGE:22527 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO Address:2000 PARK LN Box:City:PITTSBURGH State:PA ZIP:15275 Country:US Phone:412-490-8586 CAGE:22527 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER OXIDE CAS:20667-12-3 RTECS #:VW4900000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.01 MG AG/M3 ACGIH TLV:0.01 MG AG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RATS: 2820MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CONTACT W/SKIN CAUSES IRRIT,POSSIBLE BURNS ESPECIALLY IF SKIN WET/MOIST.MAY CAUSE CYANOSIS W/BLUISH SKIN.EYE/SKIN:SEVERE IRRIT,POSSIBLE BURNS.INGEST:HARMFUL.MAY CAUSE SEVERE GI TRACT IRRIT W/NAU,VOMIT ,POSSIBLE BURNS.INHAL:IRRIT RESP TRACT W/BURNING PAIN IN NOSE/THROAT,COUGH,WHEEZING,SHORTNESS OF BREATH,PULM EDEMA.(SUP) Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NOT LISTED BY ACGIH,IARC,NIOSH,NTP,OSHA. Effects of Overexposure:HARMFUL IF SWALLOWED. SKIN IRRIT, BURNS, SEVERE RESP TRACT IRRIT, SEVERE SKIN IRRIT, BURNS, CYANOSIS W/BLUISH SKIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. TARGET ORGANS:NONE ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS LIFT UPPER/LOWER LIDS.GET MED AID IMMED.DONT ALLOW VICTIM TO RUB OR KEEP EYE CLSD.SKIN:GET MED AID IMMED.IMMED FLUSH W/PLENTY OF SOAP/WATER FOR @LEA ST 15MINS WHILE REMOVING CONTMAIN CLOTH/SHOES.INGSET:CONSC/ALERT GIVE 2-4CUPFULS OF MILK/WATER.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.GET MED AID IMMED.INHAL:GET MED AID IMMED.REMOVE TO FRESH(SUPPLE) ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:NA Lower Limits:N/AVAI Upper Limits:N/AVAI Extinguishing Media:SM:USE DRY CHEMICAL,CO2,WATERSPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT CONTCT W/SKIN/EYES.WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) TO PREVENT CONTACT W/THERM DECMPO PRODUCTS. Unusual Fire/Explosion Hazard:DANGER!STRONG OXIDIZER.CONTACT W/OTHER MATL MAY CAUSE FIRE.COTNACT W/COMBUST MATLS MAY CAUSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PPE/EQPMT.VAC/SWEEP UP MATL.PLACE INTO SUITABLE DISPO CNTNR.AVOID GENERATING DUSTY CONDITIONS.REMOVE ALL IGN SOURCES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQU VENTI.KEEP CNTNR TIGHTLY CLSD.AVOID CLOTH/COMBUST MATLS CONTACT.DONT GET IN EYE/SKIN.DONT INGEST/INHAL.DONT STORE NEAR COMBUST MATLS. Other Precautions:KEEP AWAYF ROM SOURCES OF IGN.DONT STORE NEAR COMBUST MATLS.STORE IN TIGHTLY CLSD CNTNRS.STORE IN COOL DRY WELL-VENTI AREA AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESP REGS FOUND IN 29CFR1910.134.ALWAYS USE NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GEN/LOC EXHAUS VENTI TO KEEP AIRBORNE CONCEN BEL PERMISSIBLE EXPO LIMITS. Protective Gloves:IMPERVIOUS GLOVES Eye Protection:APPROPRIATE PROT EYEGLASS,CHEM SAF GOGG Other Protective Equipment:EYEWARE IAW 29CFR1910.133.WEAR APPROPRIATE PROTECTIVE CLOTH TO PREVENT SKIN EXPO. Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG. Supplemental Safety and Health HEALTH:INHAL:CHRONIC:NOT AVAI.CHRONIC INHAL/INGEST CAUSE ARGYRIA CHARACT-BLUE-GRAY PIGMENTATION OF SKIN/MUC MEMB.LOC ARGYRIA-PERM DISCOLORATION OF SKIN,PIGMENTATION PERM. 1STAID:AIR IMMED.NOT BREATH G IVE ART RESP;DIFFI BREATH GIVE OXY.DR:TREAT SYMPT/SUPPORT. INCOMPA:(IGN),H2S(IGN),HYDRAZINES,AMINES,S,METAL SULFIDES,CO. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:N/AVAI Melt/Freeze Pt:M.P/F.P Text:392F,200C Decomp Temp:Decomp Text:N/AVAI Vapor Pres:N/AVAI Vapor Density:N/AVAI Spec Gravity:7.14 pH:N/AVAI Viscosity:N/AVAI Evaporation Rate & Reference:N/AVAI Solubility in Water:NEGLIGIBLE IN WATER Appearance and Odor:BROWNISH, BLACK HEAVY POWDER. SOLID, ODORLESS Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUST MATLS,ORG MATLS,REDUCING AGENTS.AMMONIA(RXS DANGEROUSLY),GRIND W/METAL SULFIDES,SELENIUM,SULFUR,PHOSPHORUS(SUPP) Stability Condition to Avoid:ABSORBS CO2 FROM AIR.CONTACT W/MATL CAUSE FIRE. Hazardous Decomposition Products:OXYGEN, SILVER FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:NONE SPECIFIED BY MANUFACTURER. HMIS:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.