FERRELLGAS -- PROPANE -- 6830-00-985-7278
===================== Product Identification ===================== Product ID:PROPANE MSDS Date:06/01/1993 FSC:6830 NIIN:00-985-7278 Status Code:A === Responsible Party === Company Name:FERRELLGAS Address:1 LIBERTY PLAZA City:LIBERTY State:MO ZIP:64068-2970 Country:US Info Phone Num:816-792-1600 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:0CH06 === Contractor Identification === Company Name:ESPECIAL GAS INC Address:517 N 4TH ST Box:298 City:ABILENE State:TX ZIP:79601-6028 Country:US Phone:800 588-1126 / 915-675-5311 Contract Num:SP0450-00-M-SE27 CAGE:1L0Z6 Company Name:FERRELLGAS Address:1 LIBERTY PLAZA Box:City:LIBERTY State:MO ZIP:64068-2970 Country:US Phone:816-792-1600; 816-792-6916 CAGE:0CH06 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1800 MG/M3;1000 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ROUTES OF ENTRY: SKIN-FROSTBITE (PRIMARY); LUNGS-INHALATION (PRIMARY). CLASSIFIED AS A SIMPLE ASPHYXIANT, MINIMAL OXYGEN CONTENT SHOULD BE 19.5% BY VOLUME UNDER NORMAL ATMOSPHERIC CONDITIONS (ACGIH). CENTRAL NERVOUS SYSTEM DEPRESSANT. MAY CAUSE ANEMIA AND IRREGULAR HEART RHYTHM. Explanation of Carcinogenicity:NON- CARCINOGENIC Effects of Overexposure:HIGH CONCENTRATION CAN LEAD TO SYMPTOMS RANGING FROM DIZZINESS TO ANESTHESIA AND RESPIRATORY ARREST IF INHALED. EYES CAN BE MODERATELY IRRITATED. Medical Cond Aggravated by Exposure:CAUTION IS RECOMMENDED FOR PERSONNEL WITH PRE-EXISTING CENTRAL NERVOUS SYSTEM OR CHRONIC RESPIRATORY DISEASES. ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER AIR, OXYGEN, OR CPR. SKIN: KEEP AFFECTED AREA WARM AND SUBMERGE IN LUKEWARM WATER. FLUSH EYES IMMEDIATELY WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:=-104.4C, -156.F Autoignition Temp:=504.4C, 940.F Lower Limits:2.15% Upper Limits:9.60% Extinguishing Media:DRY CHEMICAL CLASS A-B-C, CO2, WATER SPRAY OR HALON. Fire Fighting Procedures:STOP FLOW OF GAS. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. USE WATER SPRAY TO DISPERSE UNIGNITED GAS OR VAPOR. USE SELF-CONTAINED BREATHING APPARATUS IN CONFINED SPACES. EVACUATE AREA UNTIL GAS DISSIPATES COMPLETELY. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID AND GAS UNDER PRESSURE. MAY FORM EXPLOSIVE MIXTURES WITH AIR. CONTAINERS EXPOSED TO FIRE OR EXCESSIVE HEAT MAY RUPTURE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP PUBLIC AWAY. SHUT OFF GAS SUPPLY. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. DISPERSE WITH WATER SPRAY. CONTACT BETWEEN SKIN AND LIQUID PROPANE CAN CAUSE FREEZING OF TISSUE. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS AWAY FROM HEAT SOURCES. STORE IN UPRIGHT POSITION. CONTAINERS SHOULD NOT BE DROPPED. CONTAINER TEMPERATURE SHOULD NOT EXCEED 130F (54.4C).TRAINING: IN THE INTEREST OF SAFETY, ALL PERS ONS EMPLOYED IN HANDLING PROPANE GAS MUST BE TRAINED IN PROPER HANDLING AND OPERATING PROCEDURES. Other Precautions:CLOSE CONTAINER SERVICE VALVE WHEN NOT IN USE AND WHEN EMPTY. INSTALL PROTECTIVE CAP WHEN NOT CONNECTED FOR USE. CONTAINER, EVEN THOSE THAT HAVE BEEN EMPTIED CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILLL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH OR MSHA APPROVED EQUIPMENT WHEN AIRBORNE EXPOSURE LIMITS ARE EXCEEDED. Ventilation:PROVIDE ADEQUATE VENTILATION TO MEET TLV REQUIREMENTS AND TO KEEP CONC. IN AIR BELOW 25% OF L.E.L. MECHANICAL VENTILATORS MUST MEET N.E.C. EXPLOSION PROOF STD. Protective Gloves:IMPERVIOUS PLASTIC OR NEOPRENE-COATED CANVAS. Eye Protection:FACE SHIELD OR CHEMICAL GOGGLES WHEN DOING MAINTENANCE IN LIQUID PROPANE SYSTEM Work Hygienic Practices:AVOID BREATHING GAS, SECURE AND EVACUATE AREA IF GAS IS SMELLED. Supplemental Safety and Health THE TRAINING IN PROPER HANDLING AND OPERATING PROCEDURES IN A PROPANE GAS SYSTEM SHOULD BE DOCUMENTED. ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:=-42.2C, -44.F Vapor Pres:208 PSIG(MAX)@100F Vapor Density:1.52 Spec Gravity:0.51 Evaporation Rate & Reference:DIFFUSES READILY, <1 Solubility in Water:SLIGHTLY Appearance and Odor:CLEAR, UNPLEASANT ODOR SIMILAR TO GARLIC (ODORIZED BY ETHYL MERCAPTAN) Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HEAT, SPARKS, FLAME AND BUILD-UP OF STATIC ELECTRICITY. PREVENT VAPOR ACCUMULATION. Hazardous Decomposition Products:CARBON MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:THIS MATERIAL IS HAZARDOUS AS DEFINED BY OSHA'S HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. RCRA: THIS PRODUCT IS NOT SUBJECT TO THE 40 CFR PART268.30 LAND BAN ON THE DISPOSAL OF CERTAIN HAZARDOU S WASTES. THIS PRODUCT DOES NOT CONTAIN CFC'S, HFC'S OR OTHER OZONE DEPLETING COMPOUNDS AS DEFINED BY THE EPA. NFPA HAZARD RATING: HEALTH HAZARD= SLIGHT. FIRE HAZARD= SEVERE. REACTIVITY= MINIMAL. EXPO SURE LIMITS: ACGIH: CLASSED AS A SIMPLE ASPHYXIANT. OSHA PEL+ 1,000 PPM, 1,800 MG/M3, 8 HR TWA. ===================== Ecological Information ===================== Ecological:REP0RTABLE QUANTITY (RQ). EPA REGULATION 40 CFR 302 (CERCLA SECTION 102): NO RQ FOR PRODUCT OR ANY CONSTITUENT GREATER THAN 1% OR ).1% (CARCINOGEN). THRESHOLD PLANNING QUANTITY (TPQ). EPA REGULATION 4 0 CFR 355 (SARA SECTIONS 301-304): NO TPQ FOR PRODUCT OR ANY CONSTITUTENT GREATER THAN 1% OR 0.1% (CARCINOGEN). TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA SECTION 313): NO TOXIC CHEMICAL IS PRESENT GREATER THAN % OR 0.1% (CARCINOGEN). HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA SECTIONS 311-312). EPA HAZARD CLASSIFICATION CODE: ACUTE HAZARD, FIRE HAZARD, PR ESSURE HAZARD. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED BURNING IN COMPLIANCE WITH APPLICABLE CODES AND LAWS. CONTACT SUPPLIER. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: LIQUEFIED PETROLEUM GAS; HAZARD CLASS: FLAMMABLE GAS; UN 1075; LABEL REQUIRED: FLAMMABLE GAS, CLASS 2.1. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.